Non-Relativistic QED Theory of the van der Waals Dispersion Interaction

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Éditeur :

Springer


Collection :

SpringerBriefs in Molecular Science

Paru le : 2016-09-29

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Description

This book provides details of the calculation of the interaction between two neutral polarizable atoms or molecules using molecular quantum electrodynamics (QED). To better understand the origin of this force, it briefly outlines molecular QED theory, the well-known van der Waals dispersion potential first evaluated by Casimir and Polder, who accounted for retardation effects. It presents different calculation schemes for the evaluation of the dispersion potential and also discusses energy shifts involving electric quadrupole and octupole moments, along with discriminatory dispersion potentials. Further, it explores in detail non-additive dispersion interaction energies between three-bodies, as well as the effects of higher multipole moment correction terms, and provides results for specific geometries such as collinear and equilateral triangles. Lastly, it computes near and far-zone asymptotic limits for both pair and many-body potentials, with the former shown to agree with less rigorous semi-classical calculations.
Pages
105 pages
Collection
SpringerBriefs in Molecular Science
Parution
2016-09-29
Marque
Springer
EAN papier
9783319456041
EAN PDF
9783319456065

Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
10
Taille du fichier
1659 Ko
Prix
52,74 €
EAN EPUB
9783319456065

Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
10
Taille du fichier
1382 Ko
Prix
52,74 €