Téléchargez le livre : Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene

Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene

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Éditeur :

Springer


Collection :

Springer Theses

Paru le : 2017-01-05

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Description

This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.
Pages
141 pages
Collection
Springer Theses
Parution
2017-01-05
Marque
Springer
EAN papier
9789811007729
EAN PDF
9789811007736
Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
14
Taille du fichier
6615 Ko
Prix
94,94 €
EAN EPUB
9789811007736
Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
14
Taille du fichier
2632 Ko
Prix
94,94 €

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