Molecular Conformation and Organic Photochemistry

Time-resolved Photoionization Studies

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Éditeur :

Springer


Collection :

Springer Theses

Paru le : 2012-05-17



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Description
Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecule relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation.
Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics.
Pages
124 pages
Collection
Springer Theses
Parution
2012-05-17
Marque
Springer
EAN papier
9783642293801
EAN EPUB
9783642293818

Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
12
Taille du fichier
1587 Ko
Prix
94,94 €