Téléchargez le livre : MWW-Type Titanosilicate

MWW-Type Titanosilicate

Synthesis, Structural Modification and Catalytic Applications to Green Oxidations de

Éditeur :

Springer


Collection :

SpringerBriefs in Molecular Science

Paru le : 2013-08-04

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Description

This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.
Pages
125 pages
Collection
SpringerBriefs in Molecular Science
Parution
2013-08-04
Marque
Springer
EAN papier
9783642391149
EAN EPUB
9783642391156
Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
12
Taille du fichier
2621 Ko
Prix
52,74 €

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